Pedro's Universe

You'd have to actually get one to stay still and listen to you. You can't just come up to one and talk because secret lairs, and when you do manage to talk you're still aligned on opposite sides so they don't want to listen. That said, there have been some mysterious villain disappearances followed by mysterious hero appearances that had suspiciously similar powersets to the disappeared villain's. Also yes to being too cynical and probably to getting themselves killed.